A MILD METHOD FOR CONVERSION OF EPOXIDES INTO ALPHA-CHLORO KETONES

被引：10

作者：

RAINA, S ^{[1
]}

BHUNIYA, D ^{[1
]}

SINGH, VK ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(00)61116-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Epoxides on treatment with DMSO, oxalyl chloride, and 10 mole % of methanol in the presence of triethylamine at -60-degrees-C are converted to alpha-chloro ketones in high yield.

引用

页码：6021 / 6022

页数：2

共 8 条

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[2] CATALYTIC ENANTIOSELECTIVE SYNTHESIS OF (3S)-2,3-OXIDOSQUALENE
COREY, EJ
YI, KY
MATSUDA, SPT
[J]. TETRAHEDRON LETTERS, 1992, 33 (17) : 2319 - 2322
[3] A STABLE AND EASILY PREPARED CATALYST FOR THE ENANTIOSELECTIVE REDUCTION OF KETONES - APPLICATIONS TO MULTISTEP SYNTHESES
COREY, EJ
BAKSHI, RK
SHIBATA, S
CHEN, CP
SINGH, VK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (25) : 7925 - 7926
[4] FERRIC-CHLORIDE IN ETHER - CONVENIENT REAGENT FOR CONVERSION OF EPOXIDES INTO CHLOROHYDRINS
KAGAN, J
FIRTH, BE
SHIH, NY
BOYAJIAN, CG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (02) : 343 - 344
[5] MANCUSO AJ, 1981, SYNTHESIS-STUTTGART, P165
[6] D2H-BISHOMOHEXAPRISMANE (GARUDANE) - DESIGN OF THE FACE-TO-FACE 2+2 DIMER OF NORBORNADIENE
MEHTA, G
PADMA, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) : 7230 - 7232
[7] OLAH GA, 1979, TETRAHEDRON LETT, P3653
[8] SINGH VK, 1992, SYNTHESIS

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