NEW ACTINIDE HYDROGEN TRANSITION-METAL COMPOUNDS - SYNTHESIS OF [K(C12H24O6)][(ETA-C(5)ME(5))(2)(CL)UH6RE(PPH(3))(2)] AND THE CRYSTAL-STRUCTURE OF ITS BENZENE SOLVATE

被引：11

作者：

CENDROWSKIGUILLAUME, SM

LANCE, M

NIERLICH, M

VIGNER, J

EPHRITIKHINE, M

机构：

[1] CEA SACLAY,CHIM URANIUM LAB,CNRS,URA 331,F-91191 GIF SUR YVETTE,FRANCE

[2] CEA SACLAY,CHIM MOLEC SERV,CRISTALLOG LAB,CNRS,URA 331,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 14期

关键词：

D O I：

10.1039/c39940001655

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound is isolated from the reaction of [{U(C(5)Me(5))(2)(mu-Cl)}(3)] with [K(18-crown-6)][ReH6(PPh(3))(2)] (18-crown-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane) and is oxidized by TlBPh(4) into the neutral derivative [(C(5)Me(5))(2)(Cl)UH6Re(PPh(3))(2)]; the H-1 NMR spectra reveal that in both complexes, the uranium and rhenium atoms are linked by three bridging hydrides.

引用

页码：1655 / 1656

页数：2

共 15 条

[1] SYNTHESIS, STRUCTURE, AND REACTIVITY OF HETEROMETALLIC POLYHYDRIDE COMPLEXES OF RHENIUM WITH YTTRIUM AND LUTETIUM
ALVAREZ, D
CAULTON, KG
EVANS, WJ
ZILLER, JW
[J]. INORGANIC CHEMISTRY, 1992, 31 (26) : 5500 - 5508
[2] SYNTHESIS, STRUCTURE, AND APPLICATIONS OF TRANSITION-METAL POLYHYDRIDE ANIONS
ALVAREZ, D
LUNDQUIST, EG
ZILLER, JW
EVANS, WJ
CAULTON, KG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (22) : 8392 - 8398
[3] SYNTHESIS OF A HYDRIDE-RICH URANIUM RHENIUM DIMER - [(PARA-F-C6H4)3P]2REH6U(ETA-C5H5)3
BAUDRY, D
EPHRITIKHINE, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (1-2) : 189 - 192
[4] A SERIES OF BIS(ETA-CYCLOPENTADIENYL)URANIUM(III) DICHLORO-BRIDGED-ALKALI-METAL AND DIHALOGENOBIS(ETA-CYCLOPENTADIENYL)URANATE(III) COMPLEXES - SINGLE-CRYSTAL X-RAY STRUCTURE DETERMINATION OF [UCP''2(MU-CL)2LI(PMDETA)] AND [PPH4][UCP''2CL2] [CP''= ETA-C5H3(SIME3)2-1,3, PMDETA = (ME2NCH2CH2)2NME]
BLAKE, PC
LAPPERT, MF
ATWOOD, JL
ZHANG, HM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (21) : 1436 - 1438
[5] HYDRIDE-RICH ZIRCONIUM OSMIUM AND ZIRCONIUM RHENIUM DIMERS
BRUNO, JW
HUFFMAN, JC
GREEN, MA
CAULTON, KG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (26) : 8310 - 8312
[6] SYNTHESIS OF THE 1ST HETEROBIMETALLIC RHENIUM-RUTHENIUM ETA-2-DIHYDROGEN COMPLEXES
CAZANOUE, M
HE, ZL
NEIBECKER, D
MATHIEU, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (05) : 307 - 309
[7] CHURCHILL MR, 1973, J CHEM SOC CHEM COMM, P691, DOI 10.1039/c39730000691
[8] ANIONIC TRANSITION-METAL HYDRIDES
DARENSBOURG, MY
ASH, CE
[J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1987, 27 : 1 - 50
[9] SYNTHESIS AND PROPERTIES OF A NEW CLASS OF HIGHLY REACTIVE TRIVALENT ACTINIDE ORGANO-METALLIC COMPOUNDS - DERIVATIVES OF BIS(PENTAMETHYLCYCLOPENTADIENYL)URANIUM(III)
FAGAN, PJ
MANRIQUEZ, JM
MARKS, TJ
DAY, CS
VOLLMER, SH
DAY, VW
[J]. ORGANOMETALLICS, 1982, 1 (01) : 170 - 180
[10] STUDY OF MODERATELY RAPID CHEMICAL EXCHANGE REACTIONS BY MEANS OF NUCLEAR MAGNETIC DOUBLE RESONANCE
FORSEN, S
HOFFMAN, RA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (11) : 2892 - &

← 1 2 →