INSERTION OF PHENYL AZIDE AND DIPHENYLDIAZOMETHANE INTO BIS(CYCLOPENTADIENYL)ZIRCONACYCLOPENTANES - CRYSTAL-STRUCTURE OF AN 18-ELECTRON ALKYL ZIRCONOCENE TRIAZENIDO COMPLEX

被引：29

作者：

LUKER, T ^{[1
]}

WHITBY, RJ ^{[1
]}

WEBSTER, M ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 492卷 / 01期

关键词：

AMINE; EARLY TRANSITION METALS; GROUP; 4; METALLACYCLE; ZIRCONIUM; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)05220-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The terminal nitrogen atoms of phenyl azide and diphenyldiazomethane insert into one of the carbon-zirconium bonds of zirconacyclopentanes to give novel 18 electron azazirconacycles that are very stable towards hydrolysis. An X-ray diffraction study has been carried out on the triazenido alkyl zirconocene complex 5. Hydrogenolysis of the diphenyldiazomethane inserted zirconacycle gives a primary amine, the first example of the direct formation of amines from organozirconium compounds.

引用

页码：53 / 57

页数：5

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