SOLVATION OF MOLYBDENUM(O)-DIIMINE-TETRACARBONYL COMPLEXES

被引：7

作者：

ALI, RB

BURGESS, J

机构：

[1] Chemistry Department, University of Leicester, Leicester

来源：

TRANSITION METAL CHEMISTRY | 1993年 / 18卷 / 01期

关键词：

D O I：

10.1007/BF00136040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solubilities of molybdenum(O)-diimine-tetracarbonyl complexes containing pyridyl-primary amine Schiff base or substituted 1,4-diazabutadiene ligands are reported, for a variety of non-aqueous solvents, and for toluene + heptane, toluene + methanol, and methanol-rich methanol + water mixed solvents. Enthalpies and entropies of solution for several of these complexes in a selection of solvents have been derived from temperature variation of solubilities. These results, together with new data on solvent effects on infrared and n.m.r. (H-1, C-13, Mo-95) spectra and published data on solvatochromism of this family of compounds, are discussed in relation to solvation of these complexes in pure and mixed solvents.

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页码：9 / 18

页数：10

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