A NEW SYNTHETIC ROUTE TO OPTICALLY-ACTIVE ALPHA-ALKYL-2-FURYLCARBINOL AND 3-FURYLCARBINOL BY INTRAMOLECULAR DIASTEREOSELECTIVITY

被引：25

作者：

GIRODIER, LD

ROUESSAC, FP

机构：

[1] Laboratoire de Synthèse Organique - URA 482, CNRS Faculté des Sciences, Université du Maine, 72017 Le Mans Cedex, Avenue O. Messiaen

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 07期

关键词：

D O I：

10.1016/0957-4166(94)80157-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the results of intramolecular asymmetric alkylation of enantiomerically pure 2- and 3-furaldehydes containing a p-tolylsulfoxide group, thus providing an efficient method of obtaining optically active alpha-alkyl-2- and 3-furanmethanol of known configuration after cleavage of the sulfoxide group. In example, R and S alpha-phenyl-3-furanmethanol are described.

引用

页码：1203 / 1206

页数：4

共 25 条

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