THE STEREOSELECTIVE NUCLEOPHILIC-ADDITION OF CYANIDE TO THE CATIONIC RUTHENIUM COMPLEXES [(ETA-5-C5H5)L2RU=C=C(ME)PH]+ (L2 = (PME3)2 OR (PPH2CH2)2)

被引：5

作者：

DAVIES, SG

SMALLRIDGE, AJ

机构：

[1] Dyson Perrins Laboratory, Oxford, South Parks Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80060-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sodium cyanide reacts with the cationic ruthenium vinylidene complexes [(eta-5-C5H5)L2Ru = C = C(Me)Ph]+ (L2 = (PMe3)2 or (PPh2CH2)2) to form ruthenium eta-1-vinyl complexes in high yield and with a high degree of stereoselectivity. Computer modelling has been used to rationalise the selectivity obtained.

引用

页码：313 / 319

页数：7

共 11 条

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