共 11 条
- [11] Perrin DD, 1988, PURIFICATION LAB CHE
THE STEREOSELECTIVE NUCLEOPHILIC-ADDITION OF CYANIDE TO THE CATIONIC RUTHENIUM COMPLEXES [(ETA-5-C5H5)L2RU=C=C(ME)PH]+ (L2 = (PME3)2 OR (PPH2CH2)2)
被引：5
作者：
DAVIES, SG
SMALLRIDGE, AJ
机构：
[1] Dyson Perrins Laboratory, Oxford, South Parks Road
关键词：
D O I：
10.1016/0022-328X(91)80060-W
中图分类号：
O61 [无机化学];
学科分类号：
070301 ;
081704 ;
摘要：
Sodium cyanide reacts with the cationic ruthenium vinylidene complexes [(eta-5-C5H5)L2Ru = C = C(Me)Ph]+ (L2 = (PMe3)2 or (PPh2CH2)2) to form ruthenium eta-1-vinyl complexes in high yield and with a high degree of stereoselectivity. Computer modelling has been used to rationalise the selectivity obtained.
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页码：313 / 319
页数：7
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