DETERMINATION OF PESTICIDES IN ENVIRONMENTAL WATERS BY AUTOMATED ONLINE TRACE-ENRICHMENT AND LIQUID-CHROMATOGRAPHY

被引：101

作者：

PICHON, V ^{[1
]}

HENNION, MC ^{[1
]}

机构：

[1] ECOLE SUPER PHYS & CHIM IND VILLE PARIS,CHIM ANALYT LAB,CNRS,URA 437,F-75231 PARIS 05,FRANCE

来源：

JOURNAL OF CHROMATOGRAPHY A | 1994年 / 665卷 / 02期

关键词：

D O I：

10.1016/0021-9673(94)85057-7

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Automated on-line trace-enrichment, liquid chromatographic analysis and UV diode-array detection (DAD) were investigated for the determination of pesticides at the 0.1 mu g/l level in drinking and surface waters. The selection of the preconcentration parameters (sorbent, sample volume, reproducibility) is discussed. Conditions are specified for quantification methods such as using calibration graphs constructed with spiked samples, standard addition methods and a calculation method included in the DAD software depending on the sample nature. Detection limits of 0.1 mu g/l were obtained using 150 ml of river waters without any clean-up.

引用

页码：269 / 281

页数：13

共 14 条

[11] NIELEN MWF, 1989, J CHROMATOGRAPHY L A, V39, P5
[12] FULLY AUTOMATED ONLINE LIQUID-CHROMATOGRAPHIC SEPARATION SYSTEM FOR POLAR POLLUTANTS IN VARIOUS TYPES OF WATER
SLOBODNIK, J
BROUWER, ER
GEERDINK, RB
MULDER, WH
LINGEMAN, H
BRINKMAN, UAT
[J]. ANALYTICA CHIMICA ACTA, 1992, 268 (01) : 55 - 65
[13] RECOVERY OF ORGANIC-COMPOUNDS FROM LARGE-VOLUME AQUEOUS SAMPLES USING ONLINE LIQUID-CHROMATOGRAPHIC PRECONCENTRATION TECHNIQUES
SUBRA, P
HENNION, MC
ROSSET, R
FREI, RW
[J]. JOURNAL OF CHROMATOGRAPHY, 1988, 456 (01): : 121 - 141
[14] PRE-CONCENTRATION AND LC ANALYSIS OF CHLOROPHENOLS, USING A STYRENE-DIVINYL-BENZENE COPOLYMERIC SORBENT AND PHOTOCHEMICAL-REACTION DETECTION
WERKHOVENGOEWIE, CE
BOON, WM
PRAAT, AJJ
FREI, RW
BRINKMAN, UAT
LITTLE, CJ
[J]. CHROMATOGRAPHIA, 1982, 16 : 53 - 59

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