Inertial effects in discrete sites model of rotational freedom. Autocorrelation function and dipolar absorption

被引：76

作者：

Lassier, B. ^{[1
]}

Brot, C. ^{[1
]}

机构：

[1] Fac Sci, Chim Phys Lab, Orsay, France

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 1卷 / 12期

关键词：

D O I：

10.1016/0009-2614(68)85051-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Taking into account the finite character of the molecular moment of inertia, a model is presented for the angular motion of molecules submitted to thermal collisions in a multi-well potential. A correlation function is calculated, which has the following spectral consequences: an absorption due to the libration of the molecules in the wells is superimposed on a Debye-Kauzmann-type absorption. and. contrary to the Debye behavior. the transparency of the substance is recovered at higher frequencies. These properties agree with recent experimental data in the submillimeter region.

引用

页码：581 / 584

页数：4