SELECTIVE CATALYTIC BEHAVIOR OF CU-NI ALLOY SURFACE

被引:12
作者
MORANLOPEZ, JL [1 ]
BENNEMANN, KH [1 ]
机构
[1] FREIE UNIV BERLIN,INST THEORET PHYS,D-1000 BERLIN 33,FED REP GER
关键词
D O I
10.1016/0039-6028(78)90244-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The selective catalytic behaviour of the CuxNi1-x alloy surface is studied. The concentration dependence of the catalytic activity with respect to chemical reactions involving cracking and non-cracking of C-C bonds is calculated for a simple model for C-C bonds. Surface segregation and local environment effects on chemisorption both calculated from a microscopic electronic theory using tight-binding approximation are taken into account. © 1978.
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页码:167 / 178
页数:12
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