共 12 条
SELECTIVE CATALYTIC BEHAVIOR OF CU-NI ALLOY SURFACE
被引:12
作者:
MORANLOPEZ, JL
[1
]
BENNEMANN, KH
[1
]
机构:
[1] FREIE UNIV BERLIN,INST THEORET PHYS,D-1000 BERLIN 33,FED REP GER
关键词:
D O I:
10.1016/0039-6028(78)90244-3
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The selective catalytic behaviour of the CuxNi1-x alloy surface is studied. The concentration dependence of the catalytic activity with respect to chemical reactions involving cracking and non-cracking of C-C bonds is calculated for a simple model for C-C bonds. Surface segregation and local environment effects on chemisorption both calculated from a microscopic electronic theory using tight-binding approximation are taken into account. © 1978.
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页码:167 / 178
页数:12
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