AN INVESTIGATION INTO A PALLADIUM-CATALYZED HYDROSILYLATION OF OLEFINS

被引：36

作者：

MARINETTI, A

机构：

[1] Laboratoire Hétéroéléments et Coordination, associé au CNRS, DCPH

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(00)78203-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrosilylations of styrene and cyclopentadiene are performed in the presence of phosphetane-palladium 1:1 and 2:1 complexes. An unprecedented inhibitory effect of the second : phosphine ligand suggests a monophosphine-Pd catalyzed process which proceeds through four-coordinate intermediates.

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页码：5861 / 5864

页数：4

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