MEASUREMENT OF CLUSTER REORGANIZATION BY TIME-RESOLVED PHOTOELECTRON-SPECTROSCOPY

被引：44

作者：

SYAGE, JA

机构：

[1] The Aerospace Corporation, Los Angeles, CA 90009

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 202卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(93)85270-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An excited-state proton transfer was initiated in the molecule phenol seeded in a solvent cluster of (NH3)n and the subsequent reorganization of the solvent about the proton measured by time-resolved photoelectron spectroscopy. A shift in the broad photo-electron band on a timescale of 300 ps is attributed to a changing Franck-Condon distribution for ionization arising from reorganization of the solvent geometry.

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页码：227 / 232

页数：6

相关论文

共 27 条

[1] VIBRATIONAL-MODES AND THE DYNAMIC SOLVENT EFFECT IN ELECTRON AND PROTON-TRANSFER [J].

BARBARA, PF ;

WALKER, GC ;

SMITH, TP .

SCIENCE, 1992, 256 (5059) :975-981

[2] INTRACLUSTER REACTIONS IN PHENYLACETYLENE AMMONIA CLUSTERS INITIATED THROUGH RESONANT ENHANCED IONIZATION [J].

BREEN, JJ ;

TZENG, WB ;

KILGORE, K ;

KEESEE, RG ;

CASTLEMAN, AW .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (01) :19-24

[3] REAL-TIME PROBING OF REACTIONS IN CLUSTERS [J].

BREEN, JJ ;

PENG, LW ;

WILLBERG, DM ;

HEIKAL, A ;

CONG, P ;

ZEWAIL, AH .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (01) :805-807

[4] EXCITED-STATE PROTON-TRANSFER IN NEUTRAL MICROSOLVENT CLUSTERS - ALPHA-NAPHTHOL.(NH3)N [J].

CHESHNOVSKY, O ;

LEUTWYLER, S .

CHEMICAL PHYSICS LETTERS, 1985, 121 (1-2) :1-8

[5] EXCITED-STATE PROTON-TRANSFER IN GAS-PHASE CLUSTERS - 2-NAPHTHOL.(NH3)N [J].

DROZ, T ;

KNOCHENMUSS, R ;

LEUTWYLER, S .

JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (07) :4520-4532

[6] TIME-RESOLVED DYNAMICS OF CLUSTER ISOMERIZATION [J].

HEIDENREICH, A ;

JORTNER, J ;

OREF, I .

JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (01) :197-210

[7] EXCITED-STATE PROTON-TRANSFER IN 1-NAPHTHOL AMMONIA CLUSTERS [J].

HINEMAN, MF ;

BRUCKER, GA ;

KELLEY, DF ;

BERNSTEIN, ER .

JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (05) :3341-3347

[8] OUTER-SPHERE ELECTRON-TRANSFER REACTIONS AND FREQUENCY-DEPENDENT FRICTION [J].

HYNES, JT .

JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (16) :3701-3706

[9] FEMTOSECOND MICROSCOPIC SOLVATION DYNAMICS OF AQUEOUS-SOLUTIONS [J].

JARZEBA, W ;

WALKER, GC ;

JOHNSON, AE ;

KAHLOW, MA ;

BARBARA, PF .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (25) :7039-7041

[10] REACTIVITY OF MOLECULAR CLUSTERS IN THE GAS-PHASE - PROTON-TRANSFER REACTION IN NEUTRAL PHENOL-(NH3)N AND PHENOL-(C2H5NH2)N [J].

JOUVET, C ;

LARDEUXDEDONDER, C ;

RICHARDVIARD, M ;

SOLGADI, D ;

TRAMER, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (12) :5041-5048