AN INVESTIGATION OF THE INHERENT CHIRAL INDUCTION ABILITY OF AXIALLY CHIRAL 1,1'-BINAPHTHALENE FRAMEWORK IN THE PRELOGS ATROLACTIC ACID SYNTHESIS

被引：10

作者：

TAMAI, Y ^{[1
]}

NAKANO, T ^{[1
]}

MIYANO, S ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC ENGN,DEPT BIOCHEM & ENGN,ARAMAKI AOBA,AOBA KU, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 05期

关键词：

D O I：

10.1246/cl.1992.807

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the Prelog's atrolactic acid synthesis using 2'-substituted 1,1'-binaphthalen-2-ols as the chiral auxiliaries, the sense of the diastereoselection could not solely be determined by the helicity of the 1,1'-binaphthalene framework. A revised steric model is proposed to explain the selectivity.

引用

页码：807 / 808

页数：2

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