A DINUCLEAR PALLADIUM COMPOUND, [PD-2(PPH(3))(2)(SC2H4S)(2)]

被引:14
作者
CAO, R
HONG, M
JIANG, F
LIU, H
机构
关键词
D O I
10.1107/S0108270194015076
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, bis(mu-1,2-ethanedithiolato-S,S':S)-bis[(triphenylphosphine)palladium(II)], is a dimer where the Pd atoms are linked by two S atoms, one from each SC2H4S2- ligand; each Pd atom is four-coordinate (one P and three S atoms) with a distorted square-planar geometry. The Pd ... Pd distance is 3.038 (2) Angstrom, and the average Pd-S and Pd-P distances are 2.332(5) and 2.281 (5) Angstrom, respectively.
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页码:1280 / 1282
页数:3
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