REGIOSELECTIVE AND STEREOSELECTIVE CROSS-COUPLING REACTION OF OPTICALLY-ACTIVE ALLYLSILANES - STEREOCONTROL OF PALLADIUM-MEDIATED S-E' REACTIONS

被引：46

作者：

HATANAKA, Y ^{[1
]}

GODA, K ^{[1
]}

HIYAMA, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 08期

关键词：

D O I：

10.1016/0040-4039(94)88043-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active allylsilanes undergo the gamma-regioselective cross-coupling reactions with aryl triflates in the presence of a palladium catalyst and a fluoride salt; the absolute configuration and % ee of the coupled products could be controlled by the choice of the fluoride salt and the polarity of the solvent.

引用

页码：1279 / 1282

页数：4

共 20 条

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