AGGREGATES OF HEXAKIS(N-HEXYLOXY)TRIPHENYLENE SELF-ASSEMBLE IN DODECANE SOLUTION - INTERCALATION OF (-)-MENTHOL 3,5-DINITROBENZOATE INDUCES FORMATION OF HELICAL STRUCTURES

被引：43

作者：

GALLIVAN, JP ^{[1
]}

SCHUSTER, GB ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT CHEM,ROGER ADAMS LAB,URBANA,IL 61801

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 08期

关键词：

D O I：

10.1021/jo00113a023

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Concentrated dodecane solutions of hexakis(n-hexyloxy)triphenylene form columnar aggregates as evidenced by optical spectroscopy. Addition of either ethyl 3,5-dinitrobenzoate, (+)-2'-octyl 3,5-dinitrobenzoate, (-)-2'-butyl 3,5-dinitrobenzoate, or (-)-menthol 3,5-dinitrobenzoate to these solutions results in the formation of charge-transfer complexes as shown by examination of their optical spectra. Investigation of the circular dichroism spectra of the charge-transfer complexes Suggests that intercalation of the menthol ester in the columnar aggregate induces a helical twist to the structure.

引用

页码：2423 / 2429

页数：7