CRYSTAL ENGINEERING IN 2 DIMENSIONS - DESIGN OF AMPHIPHILES FOR ORDERED FILMS

被引：16

作者：

ECKHARDT, CJ

PEACHEY, NM

SWANSON, DR

KIM, JH

WANG, J

UPHAUS, RA

LUTZ, GP

BEAK, P

机构：

[1] IOWA STATE UNIV SCI & TECHNOL,AMES LAB,AMES,IA 50011

[2] UNIV ILLINOIS,DEPT CHEM,URBANA,IL 61801

来源：

LANGMUIR | 1992年 / 8卷 / 11期

关键词：

D O I：

10.1021/la00047a003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The results of an experimental and calculative study of a new, rigidified amphiphile designed to form a well-ordered, two-dimensional Langmuir-Blodgett monolayer crystal are reported. The packing of the amphiphile is shown by atomic force microscopy to be closer to hexagonal than found for a stearic acid monolayer. The true planar space group is pl. The results essentially mirror those obtained from an atom-atom potential calculation of the packing of the amphiphile. The investigation demonstrates the utility of designing amphiphiles to 'engineer" specific planar lattices.

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页码：2591 / 2594

页数：4

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