EXCITATION LOCALIZATION IN MIXED RHODIUM-CHELATES

被引：15

作者：

GIESBERGEN, CPM

SITTERS, R

FREI, G

ZILIAN, A

GUDEL, HU

GLASBEEK, M

机构：

[1] UNIV AMSTERDAM,PHYS CHEM LAB,NIEUWE ACHTERGRACHT 127,1018 WS AMSTERDAM,NETHERLANDS

[2] UNIV BERN,INST INORGAN CHEM,CH-3000 BERN 9,SWITZERLAND

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 197卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(92)85799-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Optically detected magnetic resonance experiments have been performed for photo-excited [Rh(thpy)2(bpy)]+ doped in a single crystal of [Rh(phpy)2(bpy)]PF6. The results provide unambiguous evidence for a photo-induced triplet state excitation, localized on one of the thienylpyridyl anions chelated to Rh3+. The zero-field splitting parameters of the thienylpyridyl anion in the phosphorescent triplet state were determined to be \D\ = 3445 MHz and \E\ = 865 MHz.

引用

页码：451 / 456

页数：6

共 26 条

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