ATMOSPHERIC GAS AEROSOL EQUILIBRIUM .1. THERMODYNAMIC MODEL

被引:279
作者
KIM, YP
SEINFELD, JH
SAXENA, P
机构
[1] CALTECH,DEPT CHEM ENGN,PASADENA,CA 91125
[2] ELECT POWER RES INST,PALO ALTO,CA 94303
关键词
D O I
10.1080/02786829308959628
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A rigorous and computationally efficient thermodynamic model that estimates the state and composition of atmospheric inorganic species between the gas and aerosol phases is presented. The estimation of important thermodynamic properties, equilibrium constants, ionic activity coefficients, water activity, and deliquescence points is described. Various sources and estimation methods for inorganic gas-liquid-solid equilibrium properties are compared and optimal approaches for the new equilibrium routine are incorporated.
引用
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页码:157 / 181
页数:25
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