SYNTHESES OF CONFERTIFOLIN, WINTERIN AND ISODRIMENIN CONGENERS FROM PODOCARPIC ACID

被引：12

作者：

CAMBIE, RC

GRIMSDALE, AC

RUTLEDGE, PS

WOODGATE, PD

机构：

[1] Department of Chemistry, University of Auckland, Auckland

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 03期

关键词：

D O I：

10.1071/CH9900485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Podocarpic acid (11) has been converted into the congener (5) of confertifolin (4) through the o-quinone (29) formed by oxidations of the catechol monoether (15) and the 13-amine (16) with Fremy’s salt. Oxidation of the methyl ether (12) afforded the p-quinone (44) which was converted into the congener (6) of winterin (7). Podocarpic acid has also been converted into the congener (8) of isodrimenin (9) through the catechol derivative (37). © 1990 ASEG.

引用

页码：485 / 501

页数：17