SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL KEGGIN-TYPE ISOPOLYOXOMOLYBDATE [BU(4)N](6)[H3O](2)[MO13O40](2)

被引：6

作者：

JIN, XL ^{[1
]}

TANG, KL ^{[1
]}

NI, HH ^{[1
]}

TANG, YQ ^{[1
]}

机构：

[1] BEIJING UNIV,INST PHYS CHEM,BEIJING 100871,PEOPLES R CHINA

来源：

POLYHEDRON | 1994年 / 13卷 / 15-16期

关键词：

D O I：

10.1016/S0277-5387(00)88158-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solid-state reaction of (NH4)(6)Mo7O24.4H(2)O with Bu(4)NBr and NH2OH.HCl at low temperature yields an isopolyoxomolybdate [Bu(4)N](+)(6)[H3O](+)(2)[Mo13O40](4-)(2), the structure of which has been determined by X-ray crystallography. The title compound contains two [Mo13O40](4-) anions which have different symmetry. Both anions have Keggin-type structures with a molybdenum atom centre.

引用

页码：2439 / 2441

页数：3

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