AN ACTIVE-SITE MODEL FOR CALCIUM(II)-CONTAINING QUINOPROTEINS

被引：9

作者：

ITOH, S ^{[1
]}

HUANG, X ^{[1
]}

KAWAKAMI, H ^{[1
]}

KOMATSU, M ^{[1
]}

OHSHIRO, Y ^{[1
]}

FUKUZUMI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Ca2+ complexes of PQQ-2,9-dimethyl ester and its iminoquinone derivative have been synthesised and the reactivity towards alcohols examined; the oxidising ability of the quinone is significantly enhanced by binding Ca2+ and NH3, both of which are essential for quinoprotein methanol dehydrogenase activation.

引用

页码：2077 / 2078

页数：2

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