ROTATIONALLY RESOLVED PHOTODISSOCIATION SPECTROSCOPY OF MG+-AR

被引：58

作者：

SCURLOCK, CT ^{[1
]}

PILGRIM, JS ^{[1
]}

DUNCAN, MA ^{[1
]}

机构：

[1] UNIV GEORGIA,DEPT CHEM,ATHENS,GA 30602

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 09期

关键词：

D O I：

10.1063/1.470683

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The metal ion-complex Mg-24(+)-Ar has been prepared in a pulsed nozzle/laser vaporization source, mass selected with a reflection time-of-flight mass spectrometer and studied with photodissociation spectroscopy at high resolution. The (5,0) band of the A (2) Pi(r)<--X (2) Sigma(+) transition has been rotationally analyzed and the rotational constants, B '' = 0.1409(7) cm(-1) and B' = 0.1836(8) cm(-1), and spin-orbit constant, A' = 73.94(2) cm(-1), have been determined. The bond distances in the ground and excited states of the complex (r ''(0) = 2.88 Angstrom, r'(5) = 2.52 Angstrom)) compare well with the values predicted by theory, and they confirm the suspected nature of the electrostatic bonding in this system. (C) 1995 American Institute of Physics.

引用

页码：3293 / 3298

页数：6

共 78 条

[1] THE CO+CENTER-DOT-CO2 ELECTROSTATIC COMPLEX - GEOMETRY AND POTENTIAL [J].