ASYMMETRIC INTRAMOLECULAR DIELS-ALDER REACTION OF A SULFOXIMINE-SUBSTITUTED TRIENE

被引：17

作者：

CRAIG, D ^{[1
]}

GEACH, NJ ^{[1
]}

机构：

[1] RHONE POULENC AGR LTD,ONGAR CM5 0HW,ESSEX,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 12期

关键词：

BICYCLO[4.4.0]DECENE; INTRAMOLECULAR DIELS-ALDER; SULFOXIMINE; TRIENE;

D O I：

10.1016/S0957-4166(00)80016-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and thermally-induced intramolecular Diels-Alder (IMDA) reaction of (S)s-(+)-S-[(1E,7E)-1,7,9-decatrienyl]-S-phenyl-N-(p-tolylsulphonyl)sulphoximine 4 is described. A model is proposed for the cis-selectivity of the cycloaddition based on previous results from the reactions of sulphonyl-substituted trienes. The stereochemistry of the major cis-fused cycloadduct is determined by single-crystal X-ray analysis of that obtained from reaction of racemic 4.

引用

页码：1177 / 1180

页数：4

共 9 条

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