MECHANISTIC MODELING OF EPOXY AMINE KINETICS .1. MODEL-COMPOUND STUDY

被引：149

作者：

MIJOVIC, J

FISHBAIN, A

WIJAYA, J

机构：

[1] Department of Chemical Engineering, Polytechnic University, New York 11201, 333 Jay Street, Brooklyn

来源：

MACROMOLECULES | 1992年 / 25卷 / 02期

关键词：

D O I：

10.1021/ma00028a072

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An investigation was carried out of the mechanism and rate of epoxy-amine reactions using model compounds. High-performance liquid chromatography was used to generate experimental results. A mechanistic reaction model based on the existence of different transition complexes was proposed, and the corresponding kinetic parameters were evaluated. Excellent agreement was observed between model predictions and experimental data.

引用

页码：979 / 985

页数：7

共 51 条

[1]

ARUTYUNYAN KA, 1975, VYSOKOMOL SOEDIN A+, V17, P1647

[2]

ARUTYUNYAN KA, 1974, DOKL AKAD NAUK SSSR+, V214, P832

[3]

BARTON JM, 1985, ADV POLYM SCI, V72, P111

[4] A THERMOANALYTICAL STUDY OF THE CURE CHARACTERISTICS OF AN EPOXY-RESIN SYSTEM [J].