MECHANISTIC MODELING OF EPOXY AMINE KINETICS .1. MODEL-COMPOUND STUDY

被引：149

作者：

MIJOVIC, J

FISHBAIN, A

WIJAYA, J

机构：

[1] Department of Chemical Engineering, Polytechnic University, New York 11201, 333 Jay Street, Brooklyn

来源：

MACROMOLECULES | 1992年 / 25卷 / 02期

关键词：

D O I：

10.1021/ma00028a072

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An investigation was carried out of the mechanism and rate of epoxy-amine reactions using model compounds. High-performance liquid chromatography was used to generate experimental results. A mechanistic reaction model based on the existence of different transition complexes was proposed, and the corresponding kinetic parameters were evaluated. Excellent agreement was observed between model predictions and experimental data.

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收藏

页码：979 / 985

页数：7

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