MAGNETIC-FIELD EFFECTS ON THE DYNAMIC BEHAVIOR OF A RADICAL PAIR INVOLVING A GERMYL RADICAL

被引：6

作者：

WAKASA, M

SAKAGUCHI, Y

HAYASHI, H

机构：

[1] The Institute of Physical and Chemical Research, Wako, Saitama

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 176卷 / 06期

关键词：

D O I：

10.1016/0009-2614(91)90252-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photochemical primary process and magnetic field effect of methyltriphenyl germane in a micelle have been investigated with the aid of a nanosecond laser-flash-photolysis technique. The germyl radical generated through triplet state was directly observed. The lifetime of the generated radical pair and the yield of the escaping germyl radical were increased with increasing magnetic field strength from 0 to 1.35 T. The yield at 1.35 T became 1.16 +/- 0.02 times that at 0 T.

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页码：541 / 545

页数：5

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