INSITU SCANNING TUNNELING MICROSCOPY OF COPPER DEPOSITION WITH BENZOTRIAZOLE

被引:61
作者
ARMSTRONG, MJ
MULLER, RH
机构
[1] UNIV CALIF BERKELEY LAWRENCE BERKELEY LAB,BERKELEY,CA 94720
[2] UNIV CALIF BERKELEY,DEPT CHEM ENGN,BERKELEY,CA 94720
关键词
D O I
10.1149/1.2085965
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The submicron topography of Cu deposits has been studied with scanning tunneling microscopy to investigate the effect of benzotriazole in the initial stages of deposition. The presence of benzotriazole results in a marked increase in over-potential for the deposition. It is found to eliminate the preferential growth of specific crystallographic planes and the formation of crystal facets. The number density of nuclei, determined from Fourier transforms of the surface profiles of 7 nm thick films, is found to increase with increasing overpotential of the deposition but is independent of the presence of the inhibitor.
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页码:2303 / 2307
页数:5
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