ON THE MECHANISM OF OSMIUM CATALYZED ASYMMETRIC DIHYDROXYLATION (ADH) OF ALKENES

被引：32

作者：

LOHRAY, BB

BHUSHAN, V

机构：

[1] Division of Organic Chemistry-Synthesis, National Chemical Laboratory, Pune

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)61205-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dihydroquinidine and dihydroquinine bisesters of malonic acid, adipic acid and terephthalic acids are used as chiral auxiliaries for osmium tetroxide catalyzed asymmetric dihydroxylation of alkenes. Highly stereoselective osmylation of alkenes has been rationalized on the basis of pi-pi interaction of the alkenes with the ligand.

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页码：5113 / 5116

页数：4

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