CHIRAL CATALYST CONTROLLED ADDITION OF DIALKYLZINCS TO CHIRAL ALPHA-SILOXYALDEHYDES - ASYMMETRIC-SYNTHESIS OF EITHER DIASTEREOISOMER OF MONO-PROTECTED VICINAL DIOLS

被引：26

作者：

SOAI, K

SHIMADA, C

TAKEUCHI, M

ITABASHI, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 05期

关键词：

D O I：

10.1039/c39940000567

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The extent of the asymmetric addition of dialkylzincs to chiral alpha-siloxyaldehydes is determined by the configuration of the chiral catalyst and not by the chirality of alpha-siloxyaldehydes, providing either diastereoisomer of monoprotected vicinal diols in high diastereoisomeric excess.

引用

页码：567 / 568

页数：2

共 16 条

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