REVERSIBLE COVALENT ATTACHMENT OF C-60 TO A FURAN-FUNCTIONALIZED RESIN

被引：25

作者：

NIE, B ^{[1
]}

HASAN, K ^{[1
]}

GREAVES, MD ^{[1
]}

ROTELLO, VM ^{[1
]}

机构：

[1] UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01003

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 21期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(95)00578-Z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of Merrifield's peptide resin with the sodium anion of furfuryl alcohol provides a furan-functionalized polymer resin. This polymer reacts rapidly with C-60 to provide a fullerene-substituted polymer, presumably via Diels-Alder reaction, with the furan as diene and the fullerene as dienophile. This resin is greater than two-fold more efficient in C-60 uptake, and provides a 66% increase in C-60 release upon heating, compared with the previously reported cyclopentadiene-functionalized resin.

引用

页码：3617 / 3618

页数：2