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OPTICAL-PROPERTIES OF THE MNCL64- COMPLEX FORMED IN ABCL3MN2+ PSEUDOPEROVSKITE CRYSTALS - INFLUENCE OF THE CHEMICAL PRESSURE
被引:23
作者:
DELUCAS, MCM
RODRIGUEZ, F
GUDEL, HU
FURER, N
机构:
[1] UNIV CANTABRIA,FAC CIENCIAS,DCITTYM,SECC CIENCIA MAT,E-39005 SANTANDER,SPAIN
[2] UNIV BERN,INST ANORGAN CHEM,CH-3000 BERN 9,SWITZERLAND
关键词:
D O I:
10.1016/0022-2313(94)90222-4
中图分类号:
O43 [光学];
学科分类号:
070207 ;
0803 ;
摘要:
This work reports the excitation and luminescence spectra of several ABCl3:Mn2+ crystals. The variations in the optical spectra along this series are explained by changes in the Mn-Cl distance, R, of the MnCl64- complex as a consequence of the chemical pressure. The lattice relaxation around Mn2+ and the R dependence of the Stokes shift are analysed in detail.
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页码:581 / 584
页数:4
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