Polarizable-ion model for vibrationally excited alkali halides

被引：31

作者：

Maltz, Charles ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem, Cambridge, MA 02138 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 09期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(69)87016-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The variation of dipole moment, vibrational spacings. and rotational constant with vibrational excitation is calculated for the eight halides of K and Cs, employing a polarizable ion pair model due to Rittner. The results compare well with available experimental data.

引用

收藏

页码：707 / 710

页数：4

相关论文

共 24 条

[1] ABSORPTION SPECTRUM OF GASEOUS F- AND ELECTRON AFFINITIES OF HALOGEN ATOMS [J].

BERRY, RS ;

REIMANN, CW .

JOURNAL OF CHEMICAL PHYSICS, 1963, 38 (07) :1540-&

[2] REACTIVE SCATTERING IN MOLECULAR BEAMS - VELOCITY ANALYSIS OF KBR FORMED IN K+BR2 REACTION [J].

BIRELY, JH ;

HERSCHBACH, DR .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (04) :1690-+

[3] THE DISSOCIATION ENERGIES OF GASEOUS ALKALI HALIDES [J].

BREWER, L ;

BRACKETT, E .

CHEMICAL REVIEWS, 1961, 61 (04) :425-432

[4] ATOMIC POLARIZABILITIES AND SHIELDING FACTORS [J].

DALGARNO, A .

ADVANCES IN PHYSICS, 1962, 11 (44) :281-315

[5] RADIO-FREQUENCY SPECTRUM OF KBR BY MOLECULAR-BEAM ELECTRIC-RESONANCE METHOD [J].

DELEEUW, FH ;

VANWACHE.R ;

DYMANUS, A .

JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (03) :1393-&

[6] EFFECT OF QUENCHING OF POLARIZATIONS IN POLAR DIATOMIC MOLECULES ON NUCLEAR-QUADRUPOLE COUPLING ITS VIBRATIONAL DEPENDENCE AND MOLECULAR DIPOLE MOMENTS [J].

DEWIJN, HW .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (02) :810-&

[7] INTERMOLECULAR POTENTIALS AND INFRARED SPECTRUM OF MOLECULAR COMPLEX (H2)2 [J].

GORDON, RG ;

CASHION, JK .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (03) :1190-&

[8] DIPOLE MOMENTS OF SOME ALKALI HALIDE MOLECULES BY MOLECULAR BEAM ELECTRIC RESONANCE METHOD [J].

HEBERT, AJ ;

LOVAS, FJ ;

MELENDRE.CA ;

HOLLOWEL.CD ;

STORY, TL ;

STREET, K .

JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (06) :2824-&

[9]

Herzberg G., 1950, MOL SPECTRA DIATOMIC

[10] MICROWAVE SPECTRA OF THE ALKALI HALIDES [J].

HONIG, A ;

MANDEL, M ;

STITCH, ML ;

TOWNES, CH .

PHYSICAL REVIEW, 1954, 96 (03) :629-642