REDUCTIVE CLEAVAGE OF S-S BOND BY SAMARIUM DIIODIDE - A NOVEL METHOD FOR THE SYNTHESIS OF DISULFIDES

被引：18

作者：

JIA, XS ^{[1
]}

ZHANG, YM ^{[1
]}

ZHOU, XJ ^{[1
]}

机构：

[1] HANGZHOU UNIV,DEPT CHEM,HANGZHOU 310028,PEOPLES R CHINA

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 20期

关键词：

D O I：

10.1080/00397919408010610

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Samarium diiodide reductively cleaves the S-S bond of sodium alkyl thiosulfates to give the corresponding disulfides in moderate to good yields under mild and neutral conditions.

引用

页码：2893 / 2898

页数：6

共 16 条

[1] COBALT CARBONYL CATALYZED-REACTIONS OF DISULFIDES - CARBONYLATION TO THIOESTERS AND DESULFURIZATION TO SULFIDES [J].

ANTEBI, S ;

ALPER, H .

TETRAHEDRON LETTERS, 1985, 26 (22) :2609-2612

[2] CYCLIZATION REACTIONS OF ALPHA-AMINO RADICALS DERIVED FROM N-(N',N'-DIALKYLAMINOALKENYL)BENZOTRIAZOLES AND SAMARIUM DIIODIDE [J].

AURRECOECHEA, JM ;

FERNANDEZACEBES, A .

TETRAHEDRON LETTERS, 1993, 34 (03) :549-552

[3]

BEZZI S, 1950, GAZZ CHIM ITAL, V80, P180

[4]

CHORBADJIEV S, 1981, REV ROUM CHIM, V26, P1447

[5] SAMARIUM DIIODIDE-INDUCED REDUCTION OF ELEMENTAL SELENIUM LEADING TO A SELENOLATE ANION SPECIES - A SELECTIVE SYNTHESIS OF DIACYL DISELENIDES [J].

JIA, XS ;

ZHANG, YM ;

ZHOU, XJ .

SYNTHETIC COMMUNICATIONS, 1993, 23 (10) :1403-1408

[6]

JIRO Y, 1985, NIPPON KAGAKU KAISHI, V1, P29

[7] SYNTHESIS OF 3-ALKYLIDENECEPHAM-4-CARBOXYLIC ACID-DERIVATIVES BY SAMARIUM(II) IODIDE REDUCTION [J].

KANG, HY ;

CHO, YS ;

KOH, HY ;

CHANG, MH .

SYNTHETIC COMMUNICATIONS, 1993, 23 (21) :2977-2984

[8] EFFICIENT, HIGH-YIELD OXIDATION OF THIOLS AND SELENOLS TO DISULFIDES AND DISELENIDES [J].

MCKILLOP, A ;

KOYUNCU, D ;

KRIEF, A ;

DUMONT, W ;

RENIER, P ;

TRABELSI, M .

TETRAHEDRON LETTERS, 1990, 31 (35) :5007-5010

[9]

MICHAEL S, Patent No. 339394

[10] GENERATION AND ALKYLATION OF CARBANIONS ALPHA TO THE NITROGEN OF AMINES BY A NEW METALATION PROCEDURE [J].

MURAKAMI, M ;

HAYASHI, M ;

ITO, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (03) :793-794

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