SYNTHESIS AND ENZYMATIC CONVERSION OF AN ETHER ANALOG OF MONOGALACTOSYL DIACYLGLYCEROL

被引:10
作者
HEINZ, E [1 ]
SIEBERTZ, HP [1 ]
LINSCHEID, M [1 ]
机构
[1] UNIV COLOGNE,INST ORGAN CHEM,D-5000 COLOGNE 41,FED REP GER
关键词
D O I
10.1016/0009-3084(79)90032-X
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The synthesis of 1,2-di-O-9′-octadecenyl-3-O-β-D-galactopyranosyl-sn-glycerol is described, including a detailed discussion of mass spectrometric fragmentation patterns of this and related substances. Enzymatic experiments showed that this compound is converted by plant enzymes to the 6-O-acyl derivative. The availability of the di-9-octadecynyl compound for tritium reduction will provide a substrate for studies on direct desaturation of lipid-linked acyl or alkyl chains. © 1979.
引用
收藏
页码:265 / 276
页数:12
相关论文
共 34 条