COMPARATIVE THERMAL-STABILITY OF CARBON INTERCALATION ANODES AND LITHIUM METAL ANODES FOR RECHARGEABLE LITHIUM BATTERIES

被引：123

作者：

VONSACKEN, U ^{[1
]}

NODWELL, E ^{[1
]}

SUNDHER, A ^{[1
]}

DAHN, JR ^{[1
]}

机构：

[1] SIMON FRASER UNIV,DEPT PHYS,BURNABY,BC V5A 1S6,CANADA

来源：

JOURNAL OF POWER SOURCES | 1995年 / 54卷 / 02期

关键词：

THERMAL STABILITY; SAFETY; LITHIUM ANODE; CARBON ANODES; RECHARGEABLE LITHIUM BATTERIES;

D O I：

10.1016/0378-7753(94)02076-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An accelerating rate calorimeter has been used to probe the thermal stability of LixC6 in electrolyte as a function of specific surface area, lithium content, and solvent choice. The exotherm can be qualitatively modelled based on the reaction which produces the passivating film on the carbon surface.

引用

页码：240 / 245

页数：6

共 10 条

[1] IDENTIFICATION OF SURFACE-FILMS FORMED ON LITHIUM IN PROPYLENE CARBONATE SOLUTIONS [J].

AURBACH, D ;

DAROUX, ML ;

FAGUY, PW ;

YEAGER, E .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (07) :1611-1620

[2] ANALYSIS OF SAFETY AND RELIABILITY IN SECONDARY LITHIUM BATTERIES [J].

FOUCHARD, D ;

LECHNER, L .

ELECTROCHIMICA ACTA, 1993, 38 (09) :1193-1198

[3]

Nagaura T., 1990, PROGR BATTERIES SOLA, V9, P209

[4]

OZAWA K, 1993, 10TH P INT SEM PRIM

[5] THE ELECTROCHEMICAL-BEHAVIOR OF ALKALI AND ALKALINE-EARTH METALS IN NON-AQUEOUS BATTERY SYSTEMS - THE SOLID ELECTROLYTE INTERPHASE MODEL [J].

PELED, E .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (12) :2047-2051

[6] ELECTROCHEMICAL INTERCALATION OF LITHIUM INTO GRAPHITE [J].

SHU, ZX ;

MCMILLAN, RS ;

MURRAY, JJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (04) :922-927

[7]

TANAKA K, 1993, OCT FALL M BATT DIV, P26

[8] THERMAL HAZARD EVALUATION BY AN ACCELERATING RATE CALORIMETER [J].

TOWNSEND, DI ;

TOU, JC .

THERMOCHIMICA ACTA, 1980, 37 (01) :1-30

[9]

WAINWRIGHT DS, IN PRESS J POWER SOU

[10]

WILKINSON DP, 1990, OCT FALL M EL SOC SE

← 1 →