270-MHZ NMR-STUDY ON LINEAR GRAMICIDIN-A IN DIMETHYLSULFOXIDE - NEW INTERPRETATION

被引:12
作者
HEITZ, F [1 ]
SPACH, G [1 ]
CARY, PD [1 ]
CRANEROBINSON, C [1 ]
机构
[1] PORTSMOUTH POLYTECH,BIOPHYS LABS,PORTSMOUTH PO1 2DZ,HAMPSHIRE,ENGLAND
来源
EUROPEAN JOURNAL OF BIOCHEMISTRY | 1979年 / 93卷 / 01期
关键词
D O I
10.1111/j.1432-1033.1979.tb12803.x
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
On the basis of the finding of two sets of coupling constants (8.8 Hz and 6.7 Hz) in the 270‐MHz proton magnetic resonance spectra of linear Gramicidin in dimethylsulfoxide and the comparison of its infrared spectrum with those of known conformations of alternating poly(γ‐benzyl‐D‐glutamate–γ‐benzyl‐L‐glutamate), it is proposed that the antibotic has an LD‐ribbon structure. Copyright © 1979, Wiley Blackwell. All rights reserved
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页码:135 / 139
页数:5
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