THERMAL S-DEMETHYLATION IN PALLADIUM(II) AND PLATINUM(II) COMPLEXES WITH S-METHYL N,N-DIALKYLDITHIOCARBAMATES

被引：16

作者：

FARAGLIA, G ^{[1
]}

SINDELLARI, L ^{[1
]}

SITRAN, S ^{[1
]}

机构：

[1] CNR,IST CHIM & TECNOL RADIOELEMENTI,I-35020 PADUA,ITALY

来源：

THERMOCHIMICA ACTA | 1990年 / 161卷 / 01期

关键词：

D O I：

10.1016/0040-6031(90)80287-9

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The thermal behaviour of the dithiocarbamic ester complexes [M(MeS2CNMe2)X2] (M = Pd or Pt; X = Cl or Br) and [Pd(MeS2CNEt2)Cl2] has been examined up to 1100° C. The first decomposition step involves MeX release to form the corresponding species [M(S2CNMe2)X]n and [Pd(S2CNEt2)Cl]n. The degradation intermediates have been isolated and characterized by elemental analyses and IR and NMR (1H and 13C) spectra. Their possible structure is discussed and correlated with the properties of the starting dithiocarbamic ester adducts. On heating, the mixed complexes [Pt(S2CNEt2)(MeS2CNR2)Cl] (R = Me or Et) undergo an analogous S-demethylation process, MeCl being evolved at temperatures lower than those of the same process for the [Pt(MeS2CNMe2)X2] species. © 1990.

引用

页码：63 / 73

页数：11

共 16 条

[11]

PAKHOMOVA IV, 1988, ZH OBSHCH KHIM+, V58, P647

[12]

PAKHOMOVA IV, 1984, ZH NEORG KHIM+, V29, P575

[13] MONOTHEOPHYLLINE AND MONOTHEOPHYLLINATO COMPLEXES OF PALLADIUM(II) AND THEIR INTERACTIONS WITH NUCLEOSIDES [J].

PNEUMATIKAKIS, G ;

YANNOPOULOS, A ;

MARKOPOULOS, J ;

ANGELOPOULOS, C .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1988, 152 (02) :101-106

[14] NUCLEOPHILIC DISCRIMINATION AND THE TRANS EFFECT - THE KINETICS OF DISPLACEMENT OF X FROM TRANS-[PT(L)(X)CL2]N- (L=ME2SO, ET2S, PME3, PET3, PPH3, OR ASET3, X=CL, N=1, X=MEOH, N=O) BY NEUTRAL AND ANIONIC NUCLEOPHILES [J].

TOBE, ML ;

TREADGOLD, AT ;

CATTALINI, L .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (09) :2347-2352

[15] LIGATING PROPERTIES OF COORDINATED THIOCARBOXAMIDO GROUP - SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURE OF MU-CHLORO-MU-THIOCARBOXAMIDO-DICHLOROBIS(TRIPHENYLPHOSPHINE)DIPALLADIUM.ACETONE SOLVATE [J].

TRESOLDI, G ;

BRUNO, G ;

PIRAINO, P ;

FARAONE, F ;

BOMBIERI, G .

INORGANICA CHIMICA ACTA-ARTICLES, 1981, 51 (02) :263-271

[16] MIXED-LIGAND MONOTHIO-CARBAMATO AND DITHIOCARBAMATO COMPLEXES OF PALLADIUM(II) [J].

VANDERLINDEN, JGM ;

BLOMMERDE, W ;

DIX, AH ;

PIJPERS, FW .

INORGANICA CHIMICA ACTA, 1977, 24 (03) :261-267

← 1 2 →