EFFECTS OF ORGANIC MODIFIER AND TEMPERATURE ON MICELLAR LIQUID-CHROMATOGRAPHY

被引：50

作者：

TOMASELLA, FP ^{[1
]}

FETT, J ^{[1
]}

LOVE, LJC ^{[1
]}

机构：

[1] SETON HALL UNIV,DEPT CHEM,S ORANGE,NJ 07079

来源：

ANALYTICAL CHEMISTRY | 1991年 / 63卷 / 05期

关键词：

D O I：

10.1021/ac00005a018

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The role of an added organic modifier in micellar liquid chromatography is investigated. The change in equilibria caused by the addition of an organic modifier to the micellar mobile phase is calculated. Thermodynamic property trends are examined in accordance with the three-phase model. Enthalpy-entropy compensation behavior is tested for varying amounts of added organic modifier. The change in retention mechanism as a result of added organic modifier is described.

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收藏

页码：474 / 479

页数：6

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