SYNTHESIS AND CHARACTERIZATION OF ANSA-DIMETHYLSILYLBISCYCLOPENTADIENYL TITANIUM(II) COMPLEXES - CRYSTAL-STRUCTURE OF [TI(ME2SI(C5H4)2)(CN(2,6-ME2C6H3))2]

被引：18

作者：

CUENCA, T ^{[1
]}

GOMEZ, R ^{[1
]}

GOMEZSAL, P ^{[1
]}

ROYO, P ^{[1
]}

机构：

[1] UNIV ALCALA DE HENARES, DEPT QUIM INORGAN, CAMPUS UNIV, E-28871 ALCALA DE HENARES, SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 454卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83230-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The titanium(II) adducts Ti[Me2Si(eta5-C5H4)2]L2 [L = CO (1), PMe2Ph (2), CNR (R = 2,6-Me2C6H3) (3) have been made by the reduction of Ti[Me2Si(eta5_C5H4)2]Cl2 with HgCl2-activated magnesium in THF in the presence of the ligand L. Mixed titanocene adducts Ti[Me2Si(eta5-C5H4)2]LL' (L = CO; L' = PMe2Ph (4), CNR (5)) can be prepared by the addition of ligands (PMe2Ph, CNR) to hexane solutions of Ti[Me2Si(eta5-C5H4)2](CO)2 exposed to sunlight. The crystal structure of 3 has been determined by X-ray diffraction; the phenyl groups of the isocyanide ligand are almost perpendicular to the reflection plane of the cyclopentadienyl groups.

引用

页码：105 / 111

页数：7

共 56 条

[1] FIXATION AND ACTIVATION OF CO2 AND CS2 BY CP2M(PME3)2 COMPLEXES (CP=ETA-5-CYCLOPENTADIENYL - M=TI,ZR) [J].

ALT, HG ;

SCHWIND, KH ;

RAUSCH, MD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 321 (01) :C9-C12

[2]

ALT HG, 1987, J ORGANOMET CHEM, V329, P61

[3] FORMATION AND REACTIVITY OF THE ETHYLENE COMPLEX CP2TIC2H4 - THE CRYSTAL-STRUCTURE OF (CP2TIET)2O [J].

ALT, HG ;

SCHWIND, KH ;

RAUSCH, MD ;

THEWALT, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 349 (1-2) :C7-C10

[4] ACETYLENE DERIVATIVES OF TITANOCENE [J].

ALT, HG ;

ENGELHARDT, HE ;

RAUSCH, MD ;

KOOL, LB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) :3717-3718

[5]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[6]

BADJUR CS, 1985, ORGANOMETALLICS, V4, P1929

[7] SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND ELECTROCHEMISTRY OF [1]METALLOCENOPHANE COMPLEXES, [SI(ALKYL)2(C5H4)2]TICL2,[SI(ALKYL)2(C5H4)2]ZRCL2 [J].

BAJGUR, CS ;

TIKKANEN, WR ;

PETERSEN, JL .

INORGANIC CHEMISTRY, 1985, 24 (16) :2539-2546

[8] MOLECULAR-STRUCTURE OF (CP2TI(PME3))2(MU-N2), A TITANOCENE DINITROGEN COMPLEX [J].

BERRY, DH ;

PROCOPIO, LJ ;

CARROLL, PJ .

ORGANOMETALLICS, 1988, 7 (02) :570-572

[9]

BEURSKENS PT, 1981, DIRDIF MANUAL 82

[10] A STABLE TITANACYCLO-2-PENTENE - SYNTHESIS AND STRUCTURE OF 3,3-BIS(ETA-5-CYCLOPENTADIENYL)-4,5-DIPHENYL-3-TITANATETRACYCLO-[5.5.1.0/2,6/.0/8,12]TRIDECA-4,8,11-TRIENE [J].

BHIDE, VV ;

FARONA, MF ;

DJEBLI, A ;

YOUNGS, WJ .

ORGANOMETALLICS, 1990, 9 (06) :1766-1769

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