SYNTHESIS, NUCLEAR-MAGNETIC-RESONANCE AND VIBRATION-SPECTRA OF HEXAMETHYLTRISILANES X2MESISIME2SIME3, X = H, F, CL, BR, I, PH, OME, OSO2CF3

被引:11
作者
HASSLER, K
NEUBOCK, R
机构
[1] Institut für Anorganische Chemie der T. U. Graz, A-8010 Graz
来源
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1993年 / 49卷 / 01期
关键词
D O I
10.1016/0584-8539(93)80264-B
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The syntheses, IR, Raman and Si-29 spectra of the title compounds are reported. Normal coordinate analyses have been carried out, and the calculated SiSi-force constants are compared with SiSi-coupling constants. They both increase with increasing electronegativity of the substituent X.
引用
收藏
页码:95 / 101
页数:7
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