CHEMISTRY OF INDOLE GLUCOSINOLATES - INTERMEDIACY OF INDOL-3-YLMETHYL ISOTHIOCYANATES IN THE ENZYMATIC-HYDROLYSIS OF INDOLE GLUCOSINOLATES

被引：42

作者：

HANLEY, AB ^{[1
]}

PARSLEY, KR ^{[1
]}

LEWIS, JA ^{[1
]}

FENWICK, GR ^{[1
]}

机构：

[1] INST FOOD RES, DEPT MOLEC SCI, NORWICH NR4 7UA, NORFOLK, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 08期

关键词：

D O I：

10.1039/p19900002273

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enzymic hydrolysis of 1-methoxyindol-3-ylmethyl glucosinolate (1b) proceeds via the corresponding isothiocyanate (2b), thus providing evidence for a previously unsubstantiated breakdown pathway and establishing a link with 1-methoxycyclobrassinin (4b) and related indole phytoalexins.

引用

页码：2273 / 2276

页数：4

共 17 条

[1] SYNTHESIS, REACTIONS, AND SPECTRA OF 1-ACETOXY-INDOLES,1-HYDROXY-INDOLES, AND 1-METHOXY-INDOLES [J].

ACHESON, RM ;

HUNT, PG ;

LITTLEWOOD, DM ;

MURRER, BA ;

ROSENBERG, HE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1978, (10) :1117-1125

[2] THE STRUCTURES OF SINIGRIN AND SINALBIN - AN ENZYMATIC REARRANGEMENT [J].

ETTLINGER, MG ;

LUNDEEN, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (16) :4172-4173

[3]

ETTLINGER MG, 1968, RECENT ADV PHYTOCHEM, V1

[4] GLUCOSINOLATES AND THEIR BREAKDOWN PRODUCTS IN FOOD AND FOOD PLANTS [J].

FENWICK, GR ;

HEANEY, RK ;

MULLIN, WJ .

CRC CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION, 1983, 18 (02) :123-201

[5]

Gmelin R., 1961, SUOM KEMISTIL B, VB34, P15

[6]

Gmelin R, 1962, SUOMEN KEMIST B, V35, P34

[7]

Granroth B., 1970, ANN ACADEMIAE SCIENT, V154, P1

[8]

Hanley A., 1984, CRUCIFERAE NEWSLETTE, V9, P66

[9]

HANLEY AB, 1990, PHYTOCHEMISTRY, V29, P769, DOI 10.1016/0031-9422(90)80015-9

[10] IMPROVED ISOLATION OF GLUCOBRASSICIN AND OTHER GLUCOSINOLATES [J].

HANLEY, AB ;

HEANEY, RK ;

FENWICK, GR .

JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, 1983, 34 (08) :869-873

← 1 2 →