INSERTION OF NORBORNENE INTO ARYL-PALLADIUM(II) BONDS - MECHANISTIC ASPECTS OF THE SUBSEQUENT C-H ACTIVATION

被引：47

作者：

MARKIES, BA

WIJKENS, P

KOOIJMAN, H

SPEK, AL

BOERSMA, J

VANKOTEN, G

机构：

[1] UNIV UTRECHT,DEBYE RES INST,DEPT MET MEDIATED SYNTHESIS,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS

[2] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES,CRYSTAL & STRUCT CHEM LAB,3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 19期

关键词：

D O I：

10.1039/c39920001420

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The insertion of norbornene into the Pd-C bond of the cationic phenylpalladium(II) complex [PdPh(pmdien)]OTf (2, pmdien = N,N,N',N",N"-pentamethyldiethylenetriamine, OTf = trifluoromethanesulfonate) yields a 1 : 1 enantiomeric mixture of an ortho 2-exo-norbornyl-substituted phenylpalladium(II) compound via selective, intramolecular C-H activation of the phenyl ring.

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页码：1420 / 1423

页数：4

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