INTRAMOLECULAR OXIDATIVE COUPLING OF AROMATIC-COMPOUNDS .1. OXIDATION OF DIPHENOLIC SUBSTRATES

被引：11

作者：

KRAUSS, AS

TAYLOR, WC

机构：

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1991年 / 44卷 / 09期

关键词：

D O I：

10.1071/CH9911307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of (2RS,3SR)-1-(3,5-dihydroxy-4-methoxyphenyl)-(4-hydroxy-3,5-dimethoxy-phenyl)-2,3-dimethylubtan-1-one (26) is described. Diphenolic oxidative coupling of (26) did not produce a eupodienone-type product. An aryltetralin derivative was formed instead by aryl-benzyl coupling and was further oxidized to the novel oxa spiro dienone (63). The acetoxy compound (71) derived by reduction of the carbonyl group in (26) gave a similar product (72).

引用

页码：1307 / 1333

页数：27

共 51 条

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[42] INTRAMOLECULAR OXIDATIVE COUPLING OF DIPHENOLIC, MONOPHENOLIC, AND NONPHENOLIC SUBSTRATES [J].