SYNTHESIS AND STRUCTURE OF DICHLORODI-[1,2-BIS(DIMETHYLPHOSPHINO)ETHANE]IRON(III) TETRACHLOROFERRATE(III), [FE(DMPE)2CL2]+[FECL4]-

被引：10

作者：

FIELD, LD ^{[1
]}

GEORGE, AV ^{[1
]}

HAMBLEY, TW ^{[1
]}

机构：

[1] UNIV SYDNEY,DEPT INORGAN CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

POLYHEDRON | 1990年 / 9卷 / 17期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/S0277-5387(00)84044-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Fe(DMPE)2Cl2]+[FeCl4]- was formed in high yield by the photochemical oxidation of Fe(DMPE)2Cl2 with chlorinated organic solvents CH2Cl2, CHCl3 or CCl4. Crystals of [Fe(DMPE)2Cl2]+[FeCl4]- are orthorhombic, space groupPcab, a = 16.250(3), b = 19.392(3), c = 34.451(7) Å, Z = 16, R = 0.058 (3597 F). This represents the first structural characterization of an iron(III) complex with a P4Cl2 donor set and saturated phosphine ligands. © 1990.

引用

页码：2139 / 2141

页数：3

共 25 条

[1] OLIGOPHOSPHINE LIGANDS .11. HEXACOORDINATE HALOGENOIRON COMPLEXES FEX2[P(CH2CH2CH2PME2)3] (X = CL, BR, I) [J].

ANTBERG, M ;

DAHLENBURG, L .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 104 (01) :51-54

[2] DIAMAGNETIC REVERSIBLE PARAMAGNETIC EQUILIBRIA IN SOLUTIONS OF BIS(DIALKYLPHOSPHINO)ETHANE COMPLEXES OF IRON [J].

BAKER, MV ;

FIELD, LD ;

HAMBLEY, TW .

INORGANIC CHEMISTRY, 1988, 27 (16) :2872-2876

[3] MOSSBAUER AND PREPARATIVE STUDIES OF SOME IRON(II) COMPLEXES OF DIPHOSPHINES [J].

BARCLAY, JE ;

LEIGH, GJ ;

HOULTON, A ;

SILVER, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (11) :2865-2870

[4] CRYSTAL AND MOLECULAR-STRUCTURES OF 4 BIS(DIPHOSPHINE) COMPLEXES OF IRON(II) - BIS[1,2-BIS(DIETHYLPHOSPHINO)ETHANE]DI-IODOIRON(II), DICHLORO-BIS[O-PHENYLENEBIS(DIPHENYLPHOSPHINE)]IRON(II), BIS(ACETONITRILE)BIS-[ORTHO-PHENYLENEBIS(DIPHENYLPHOSPHINE)]IRON(II) DI-IODIDE, AND IODOBIS-[ORTHO-PHENYLENEBIS(DIPHENYLPHOSPHINE)]IRON(II) IODIDEE [J].

BARCLAY, JE ;

HILLS, A ;

HUGHES, DL ;

LEIGH, GJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (11) :2871-2877

[5] CATIONIC LOW-SPIN BIS[1,2-BIS(DIALKYLPHOSPHINO)ETHANE]IRON(II) COMPLEXES [J].

BELLERBY, JM ;

MAYS, MJ ;

SEARS, PL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (13) :1232-1236

[6] PREPARATION OF [99MTC(DMPE)2CL2]+ FOR MYOCARDIAL IMAGING BY USING FE-(DMPE) COMPLEXES [J].

BERGER, R ;

SYHRE, R ;

SEIFERT, S ;

KLOTZER, D ;

MADING, P ;

MUNZE, R .

APPLIED RADIATION AND ISOTOPES, 1986, 37 (03) :197-200

[7]

CECCONI F, 1981, CRYST STRUCT COMMUN, V10, P1523

[8] SOME HYDRIDO-COMPLEXES OF IRON(II) [J].

CHATT, J ;

HAYTER, RG .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (DEC) :5507-&

[9]

COTTON AF, 1975, INORG CHEM, V14, P2467

[10]

CROMER DT, INT TABLES XRAY CRYS, V4

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