SYNTHESIS AND STRUCTURE OF DICHLORODI-[1,2-BIS(DIMETHYLPHOSPHINO)ETHANE]IRON(III) TETRACHLOROFERRATE(III), [FE(DMPE)2CL2]+[FECL4]-

被引：10

作者：

FIELD, LD ^{[1
]}

GEORGE, AV ^{[1
]}

HAMBLEY, TW ^{[1
]}

机构：

[1] UNIV SYDNEY,DEPT INORGAN CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

POLYHEDRON | 1990年 / 9卷 / 17期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/S0277-5387(00)84044-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Fe(DMPE)2Cl2]+[FeCl4]- was formed in high yield by the photochemical oxidation of Fe(DMPE)2Cl2 with chlorinated organic solvents CH2Cl2, CHCl3 or CCl4. Crystals of [Fe(DMPE)2Cl2]+[FeCl4]- are orthorhombic, space groupPcab, a = 16.250(3), b = 19.392(3), c = 34.451(7) Å, Z = 16, R = 0.058 (3597 F). This represents the first structural characterization of an iron(III) complex with a P4Cl2 donor set and saturated phosphine ligands. © 1990.

引用

页码：2139 / 2141

页数：3

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