WATER-TOLERANT UNSTABILIZED CARBANION EQUIVALENTS - BISMUTH(III) CHLORIDE-ALUMINUM PROMOTED ALKYLATIONS OF IMMONIUM CATIONS TO AMINES IN AQUEOUS-MEDIA

被引：25

作者：

KATRITZKY, AR

SHOBANA, N

HARRIS, PA

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 34期

关键词：

AQUEOUS ALKYLATION; BISMUTH; ALUMINUM; BENZOTRIAZOLE;

D O I：

10.1016/S0040-4039(00)92139-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of bismuth(III) chloride-metallic aluminum, alkyl as well as allyl halides react with N-(alkylamino)benzotriazoles at 20-degrees-C in THF-water to give the corresponding homoalkylated amines in high yields.

引用

页码：4247 / 4248

页数：2

共 15 条

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