FURTHER ON THE CHEMICAL-REDUCTION OF FE2(NO)4(MU-SR)2

被引：9

作者：

CHAU, CN ^{[1
]}

WOJCICKI, A ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

POLYHEDRON | 1993年 / 12卷 / 10期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)88222-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of Fe2(NO)4(mu-SR)2 (R = Me, Et or Bu(t)) with 2 equivalents of sodium, KH or MBR3H (M = Li, Na or K; R = Et or Bu(s)) in THF affords [Fe2(NO)4(mu-SR)2]2-, as evidenced by quantitative analysis of evolved hydrogen, conductivity measurements in MeOH and H-1 and H-2 NMR and IR nu(NO) spectroscopic data of the products. In contrast, reduction of Fe2(NO)4(mu-SR)2 with 1 equivalent of MBR3H yields products that differ from the foregoing dianions by the presence of hydrogen derived from the borohydride. The combined product characterization data do not support the formulation [Fe2(NO)4(mu-SR)2]-.

引用

页码：1261 / 1263

页数：3

共 11 条

[1] DI-TERT-BUTYLPHOSPHIDO VERSUS DIPHENYLPHOSPHIDO AS A BRIDGING LIGAND IN BINUCLEAR IRON CARBONYL-COMPLEXES - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF FE2(CO)5(MU-P(TERT-BU)2)2 AND FE2(CO)6(MU-PPH2)(MU-P(TERT-BU)2) [J].