COMPLEXING BEHAVIOR OF DIAZEPAM TOWARDS SOME BIVALENT 1ST ROW TRANSITION-METALS

被引：20

作者：

PRETI, C

TOSI, G

机构：

[1] Istituto di Chimica Generale ed Inorganica, University of Modena

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 02期

关键词：

D O I：

10.1016/0022-1902(79)80532-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation, spectroscopic and magnetic properties of some cobalt(II), nickel(II) and copper(II) halide complexes with 7-chloro-1-methyl-5-phenyl-3H-1,4-benzodiazepine-2-one are described. The most likely structure for the cobalt(II) and nickel(II) complexes is a pseudotetrahedral symmetry, whereas the copper(II) complexes are octahedral. Assignments for metal-halogen and metal-ligand stretching modes have also been made. From the magnetic properties it was concluded that the above ligand forms high-spin complexes with cobalt(II) and nickel(II). © 1979.

引用

页码：263 / 266

页数：4

共 28 条

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