STEREOSELECTIVE 1,3-DIPOLAR CYCLOADDITIONS OF PHOTOCHEMICALLY GENERATED AZOMETHINE YLIDES TO OPPOLZER CHIRAL ACRYLOYL SULTAM - AN ASYMMETRIC APPROACH TO QUINOCARCIN

被引：35

作者：

GARNER, P

HO, WB

机构：

[1] Department of Chemistry, Case Western Reserve University, Cleveland

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 13期

关键词：

D O I：

10.1021/jo00300a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photochemically generated azomethine ylides undergo highly stereoselective 1,3-dipolar cycloadditions (ds >25:1) to chiral acryloyl sultams to give the substituted 3,8-diazabicyclo[3.2.1]octane moiety of quinocarcin. © 1990, American Chemical Society. All rights reserved.

引用

页码：3973 / 3975

页数：3

共 37 条

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